Protein self-assembly induces promiscuous nucleophilic biocatalysis in Morita–Baylis–Hillman (MBH) reaction

نویسندگان
چکیده

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Protein self-assembly induces promiscuous nucleophilic biocatalysis in Morita–Baylis–Hillman (MBH) reaction

The chemical industry has seen a remarkable increase in the use of biocatalysis in recent years. Structurally dened spatial distribution of residues in proteins has offered efficient catalysis for a variety of mechanistically unique synthetic transformations. Over a period, the perspective of high specicity in enzyme catalysis has changed and led to the realization that a large population of ...

متن کامل

S-Layer Protein Self-Assembly

Crystalline S(urface)-layers are the most commonly observed cell surface structures in prokaryotic organisms (bacteria and archaea). S-layers are highly porous protein meshworks with unit cell sizes in the range of 3 to 30 nm, and thicknesses of ~10 nm. One of the key features of S-layer proteins is their intrinsic capability to form self-assembled mono- or double layers in solution, and at i...

متن کامل

Catalytic MBH reaction of β-substituted nitroalkenes with azodicarboxylates.

An unprecedented N-heterocyclic carbene (NHC) catalyzed Morita-Baylis-Hillman (MBH) reaction of β-substituted nitroalkenes and azodicarboxylates has been developed. Both β-aryl and β-alkyl nitroalkenes worked well for the reaction using 5 mol% of NHC catalyst, giving the desired α-hydrazino-α,β-unsaturated nitroalkenes in good to excellent yields.

متن کامل

Chemical reaction mediated self-assembly of PTCDA into nanofibers.

Uniform and crystalline nanofibers of perylene-3,4,9,10-tetracarboxylic dianhydride (PTCDA), an insoluble organic semiconducting molecule, have been achieved by self-assembling the molecules using chemical reaction mediated conversion of an appropriately designed soluble precursor, perylene tetracarboxylic acid (PTCA) using carbodiimide chemistry.

متن کامل

Self-regulated supramolecular assembly driven by a chemical-oscillating reaction.

A novel self-regulated supramolecular assembly (SSA) system driven by a chemical-oscillating reaction is constructed based on dynamic supramolecular interactions and the rhythm of the SSA process can be controlled by temperature.

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: RSC Advances

سال: 2016

ISSN: 2046-2069

DOI: 10.1039/c5ra23949d